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Organic chemistryWhat you need to know |
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Organic chemistryOrganic chemistry is the study of carbon compounds. Organic chemistry is so complex because... Carbon atom form very strong covalent bonds Carbon-carbon bonds can be single, double or triple Carbon atoms in organic compounds can be arranged in many different forms (isomerism) such as straight chains, branched chains or rings (cyclic or aromatic) Other elements/groups of elements can be placed on the carbon atoms to form different function groups e.g OH is functional group for alcohols. Alcohols Alcohols are not hydrocarbons and contain –OH as functional group. First few examples are methanol (CH3OH), ethanol (C2H5OH) and propanol (C3H7OH). The general formula is … CnH2n+1OH CombustionAlcohols make useful fuels just like hydrocarbons. Ethanol from fermentation is a carbon neutral fuel as the carbon dioxide produced is taken by the next crop of plants. Ethanol can be made by fermentation of plant materials (renewable). Ethanol + Oxygen ——> Carbon dioxide + Water C2H5OH + 3O2 ——> 2CO2 + 3H2O EsterificationAlcohols (OH) react with carboxylic acids (COOH) to produce ESTERS and water. Ethanoic acid + Ethanol <--> Ethyl Ethanoate + Water CH3COOH + C2H5OH <--> CH3COOC2H5 + H2O The reaction is reversible. Esters have characteristic smells (used in flavourings). Reaction with sodiumAlcohols react with sodium and hydrogen gas is produced. Unlike the reaction of sodium with water, the reaction is less vigorous. Sodium + Ethanol ——> Sodium ethoxide + Hydrogen 2Na + 2C2H5OH ——> 2C2H5ONa + H2 FermentationConditions: Glucose produced from the hydrolysis of starch, yeast and incubated in a warm environment (not higher than 37°C). Equation C6H12O6 ——> 2 C2H5OH + 2 CO2 Advantages
Disadvantages
Hydration of etheneConditions: Ethene obtained from cracking crude oil in the presence of catalyst (phosphoric acid) and high temperature and pressure. Equation C2H4 + H2O ——> 2 C2H5OH Advantages
Disadvantages
Uses of alcohol
Carboxylic acidsCarboxylic acids contain the functional group -COOH. Examples include methanoic acid (HCOOH), ethanoic acid (CH3COOH) and propanoic acid (C2H5COOH). Reactions of carboxylic acidsReact with alcohols to produce esters in a reversible reaction. Uses of carboxylic acidsVinegar contains ethanoic acid which is used in the manufacture of rayon. Oranges and lemons contain citric acid Aspirin is a carboxylic acid which is used for pain relief and prevention heart attacks. Vitamin C contains ascorbic acid which is used for pain relief and prevention heart attacks. EstersEsters are formed by replacing the H on the COOH of a carboxylic acid by a carbon atom group to give the functional group COOC. Examples include methyl methanoate (HCOOCH3) and methyl ethanoate (CH3COOCH3). Esters are used as flavourings due to their fruity odours. |